ผงโลหะสำหรับการพิมพ์ 3 มิติ

Metal powders are a critical raw material for additive manufacturing using powder bed fusion technology. This guide provides an overview of various metal powders used in 3D printing processes like selective laser melting (SLM) and electron beam melting (EBM).

Introduction to Metal Powders for AM

Metal powders enable printing of complex, high-performance metal parts using additive manufacturing.

Materials used:

• เหล็กกล้าไร้สนิม
• เหล็กกล้าเครื่องมือ
• Cobalt-chrome alloys
• โลหะผสมไทเทเนียมและไทเทเนียม
• อลูมิเนียมอัลลอยด์
• นิกเกิลซูเปอร์ลลอย
• Copper alloys

Key powder properties:

• Chemistry – Purity and composition
• รูปร่างและสัณฐานวิทยาของอนุภาค
• การกระจายขนาดอนุภาค
• Apparent density and tap density
• ความสามารถในการไหลได้
• Powder reuse

Powder production methods:

• การทำให้เป็นอะตอมก๊าซ
• การทำให้เป็นอะตอมน้ำ
• การทำให้เป็นอะตอมพลาสมา
• Electrode induction melting
• Carbonyl process
• การผสมกลไก

ผงสแตนเลส

Stainless steel powders are commonly used for printing corrosion resistant parts:

Alloy types:

• Austenitic steels like 316L, 304L
• Martensitic steels like 17-4PH
• Duplex steels like 2205
• Precipitation hardening like 17-4PH, 15-5PH

ลักษณะเฉพาะ:

• High corrosion and oxidation resistance
• Good strength and ductility
• Less prone to cracking than high-alloy steels
• Parameters like build atmosphere critical

Applications:

• Chemical and process industry parts
• Marine components
• Medical implants and devices
• Food/pharma industry parts requiring hygiene

Suppliers: Carpenter, Sandvik, Praxair, Höganäs, LPW Technology

Tool Steel Powders

Tool steels like H13 are ideal for printing wear and high-hardness parts:

Alloy types:

• Shock-resistant steels like S7
• Cold work steels like D2
• Hot work steels like H13, H11
• High speed steels like M2

ลักษณะเฉพาะ:

• Excellent hardness up to 60 HRC
• High wear resistance
• Good toughness and thermal fatigue resistance
• Require high-temperature solution annealing

Applications:

• Metal forming dies and molds
• Cutting tools and drill bits
• Wear parts and bearings
• High-temperature tooling

Suppliers: Sandvik, Erasteel, LPW Technology, Tekna Plasma Systems

Cobalt-Chrome Alloys

Cobalt-chrome powders print biocompatible implants and dental restorations:

Alloy types:

• CoCrMo like Co-28Cr-6Mo
• CoNiCrMo like Co-35Ni-20Cr-10Mo
• CoCr like Co-67Cr-28Fe

ลักษณะเฉพาะ:

• ความเข้ากันได้ทางชีวภาพที่ยอดเยี่ยมและความต้านทานการกัดกร่อน
• ความแข็งแรงและความแข็งสูง
• Wear resistance for articulating joints
• Challenging printability and cracking tendency

Applications:

• Dental copings, bridges and crowns
• Orthopedic knee and hip implants
• Fixation devices like cranial plates
• Spinal fusion hardware

Suppliers: SLM Solutions, Carpenter, Arcam EBM

Titanium Powders

Titanium powders create strong, lightweight printed parts:

Alloy types:

• Unalloyed titanium like Ti Grade 1-4
• คุณ--shal-hv ali
• Ti-6Al-7Nb alloy
• Other alpha + beta alloys

ลักษณะเฉพาะ:

• อัตราส่วนความแข็งแรงต่อน้ำหนักสูง
• ความต้านทานการกัดกร่อนที่ยอดเยี่ยม
• Good high-temperature properties
• Low density – 4.5 g/cc
• Reactive and requires inert atmosphere

Applications:

• Aerospace and motorsports components
• Medical implants and prosthetics
• Food/chemical industry parts
• Automotive parts

Suppliers: AP&C, Tekna, Carpenter Additive

Aluminum Alloys

Aluminum powders print lightweight structural or functional parts:

Alloy types:

• AlSi10Mg
• ไม่ได้เรื่อง
• Alsi12
• Scalmalloy® and other Al alloys

ลักษณะเฉพาะ:

• Low density – 2.7 g/cc
• Good strength and stiffness
• Excellent thermal conductivity
• Prone to cracking and residual stresses

Applications:

• Automotive and motorsports components
• Aerospace and space applications
• เครื่องแลกเปลี่ยนความร้อน
• Medical equipment like casts

ซัพพลายเออร์: AP&C, Sandvik, LPW Technology, ECKA Granules

นิกเกิลซูเปอร์ลลอย

Nickel superalloys like Inconel 718 print high-temperature parts:

Alloy types:

• Inconel 718
• Inconel 625
• Waspaloy
• Hastelloy x

ลักษณะเฉพาะ:

• Excellent high-temperature strength
• Good corrosion and creep resistance
• Ability to work under stress at high temps
• Challenging to process and prone to cracking

Applications:

• Turbine blades
• Combustion chamber parts
• Spacecraft components
• Nuclear/chemical industry parts

Suppliers: Praxair, Carpenter Additive, GE Additive

Copper Alloys

Copper alloys like CuCrZr print highly conductive parts:

Alloy types:

• Copper-chromium like CuCr1Zr
• Copper-nickel like CuNi2SiCr
• Bronzes like CuSn10

ลักษณะเฉพาะ:

• Excellent thermal and electrical conductivity
• ความต้านทานการกัดกร่อนที่ดี
• Antibacterial property
• Lower strengths than steels and Ni alloys

Applications:

• Electrical components like busbars
• Heat exchangers and heat sinks
• Waveguides and RF components
• Medical instruments and fixations

Suppliers: Sandvik, LPW Technology, Metalysis

Technical Specifications

Typical metal powder specifications used in AM:

Powder Production Methods

1. Gas Atomization

• Highly spherical powder
• Small particle sizes of 5-100 μm
• Used for reactive alloys like titanium

2. Water Atomization

• Irregular powder shape
• Larger particles up to 300 μm
• Lower cost process

3. Plasma Atomization

• Controlled particle shapes
• Submicron to 150 μm sizes
• High purity powder

4. Mechanical Alloying

• Elemental blending and milling
• Cost-effective for custom alloys
• Large particle sizes

ซัพพลายเออร์และราคา

• Stainless steel powders cost $45-$120 per kg
• Titanium alloy powders cost $150-$450 per kg
• Superalloys and tool steels cost $250-$600 per kg

Prices depend on alloy, quality, lot size, and purchase agreements.

Powder Handling and Storage

To prevent contamination, proper powder handling is critical:

• Use dedicated powder sieving areas
• Ensure inert atmosphere gloveboxes and hoppers
• Use conductive containers to dissipate static charges
• Ground all equipment and transport containers
• Avoid contact with oil, water, or oxygen
• Store powder in sealed containers under inert gas
• Control temperature and humidity during storage
• Follow safety precautions like PPE when handling

Proper storage extends powder reuse life.

Powder Sieving

Sieving ensures consistent particle sizes:

ประโยชน์:

• Removes satellite particles that cause defects
• Breaks up agglomerates
• Improves flow and packing density
• Reduces recyclability issues
• Removes foreign contaminants

Procedure:

• Sieve powder using mesh sizes around 20-63 μm
• Sieve using rotational or vibratory sieving
• Perform sieving under inert atmosphere
• Document remaining powder weight percentage

Sieving improves part quality by ensuring ideal powder spreadability.

Installation and Commissioning

Installing a metal AM printer with powder system involves:

• Cleaning equipment surfaces to avoid contamination
• Leak testing inert gas connections
• Checking laser or electron beam power
• Loading and testing powder recoating system
• Integrating chiller, exhaust, and service connections
• Installing monitoring and safety sensors
• Verifying powder sieving and handling systems
• Calibrating build plate levelling
• Test printing sample parts and validating quality

Vendors provide installation and commissioning support.

Operation and Best Practices

Printer operation guidelines:

• Perform regular leak checks and inert gas purity tests
• Precondition powder to ensure consistent texture
• Adjust layer thickness and laser parameters for new materials
• Closely monitor the melt pool and control part temperature
• Validate critical dimensions using test prints
• Monitor powder condition and reuse only within recommendations
• Perform regular maintenance on optics, beam delivery system and powder recoating mechanism

Personnel safety:

• Use appropriate PPE such as respirators and gloves
• Avoid contact with reactive fine metal powders
• Handle waste powder properly under inert atmosphere

Part post-processing:

• Use appropriate solution heat-treatment and ageing temperatures tailored to alloy and application
• Control ramp rates during thermal processing to relieve stresses
• Use hot isostatic pressing for complex parts if needed to improve densities
• Apply finishing steps like CNC machining and polishing

Maintenance and Inspection

Regular maintenance activities:

Daily:

• Inspect optics like mirrors, lenses, windows for damage
• Clean the build chamber and powder handling system
• Check inert gas levels and recharge if needed
• Test the sieve mechanism and powder recoater

Weekly:

• Calibrate sensors and instrumentation
• Check fasteners, electrical terminals and grounding
• Lubricate and inspect moving parts like motors and drives
• Monitor filters for replacement

Monthly:

• Leak test inert gas system using helium
• Inspect safety devices like fire detectors
• Check the CHP system health

Yearly:

• Schedule preventive maintenance with equipment vendor
• Calibrate laser power meter
• Replace filters and consumable items

Maintenance as per vendor guidelines is required to sustain part quality and equipment health.

Choosing the Right Metal Printing System

Factors to consider when selecting a metal AM machine:

1. Production Requirements

• Type of components to be produced
• Material needed based on part properties
• Production volume requirements
• Required accuracy and surface finish

2. Printer Specifications

• Supported materials and parameters
• Build size and speed
• Precision and repeatability
• Inert atmosphere management
• Automation features and controls

3. Powder Handling System

• Integrated or standalone system
• Sieving, feeding, storage and reuse capabilities
• Containment for reactive materials like titanium
• Monitoring features to avoid contamination

4. Standards Compliance

• Industry standards like ASTM F3301
• Manufacturer quality certifications
• Safety standards compliance

5. Supplier Credentials

• Proven track record in AM industry
• Local sales and technical support capabilities
• Maintenance contracts and services offered
• Operator training plans
• Overall cost of ownership

Thorough requirements analysis and comparisons of machine offerings using these criteria results in the selection of the ideal 3D metal printing system tailored to the production needs.

Pros and Cons of Metal AM

Advantages:

• High geometric complexity printed easily
• Shorter time to functional parts
• Reduced waste compared to subtractive processes
• Single setup production directly from CAD
• Lightweighting and part consolidation potential
• Performance improvements with engineered alloys
• Customization and mass customization capabilities

Disadvantages:

• High machine and material costs
• Additional post-processing steps required
• Limited size based on build chamber
• Control of internal defects can be challenging
• Material properties can vary versus wrought
• Surface finish limitations may require finishing
• Training and expertise requirements

Troubleshooting Common Metal AM Issues

คำถามที่พบบ่อย

Q: What metal alloy powders can be used for AM?

A: Stainless steels, tool steels, titanium alloys, nickel superalloys, aluminum alloys, cobalt-chrome, and copper alloys are common.

Q: What is the typical range of powder particle sizes used?

A: For PBF-LB/M processes, 10-45 microns is common, with tighter distribution around 20-45 μm.

Q: How long can metal powders last?

A: With ideal argon storage, many alloys last 1-2 years. Reuse life is shorter – 20-100 prints based on alloy.

Q: What post-processing steps are required on metal AM parts?

A: Support removal, heat treatment, surface finishing like CNC machining, polishing and coating are often required.

Q: How are reactive metal powders like titanium and aluminum handled?

A: Specialized powder handling under inert argon atmosphere is needed to prevent oxygen pickup.

Q: What are common powder contamination risks?

A: Exposure to atmosphere leading to oxygen or nitrogen pickup. Metallic particles from machining or wear. Oil and moisture.

Q: What standards are used for qualifying metal powders?

A: ASTM B214, ASTM B812, ASTM F3049, ASTM F3301, and MPIF standards.

Q: Why is powder sieving important?

A: It breaks up agglomerates, removes satellites, and provides optimum and consistent powder size for high density and surface finish.

บทสรุป

Metal powders enable additive manufacturing of advanced, high-performance components with properties better than wrought materials in some cases. A wide range of alloys from stainless steels to superalloys and titanium are available in powder form, tailored to demanding applications across aerospace, medical, automotive, and general industries. With continual improvements in alloys, quality standards, production processes, machinery, and part properties – metal AM is maturing into a core production technology globally. However, process and material expertise and rigorous quality control are essential to realize the full benefits. As more experience is gained, metal AM provides unprecedented capabilities to manufacture complex and customized parts with greater design freedom and shorter lead times.

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